The 2019 Open Champion will be on course in Rome from 7.05am.
Shane Lowry will be on course early tomorrow morning for Team Europe at the Ryder Cup.
The Clara man has been picked by captain Luke Donald to take on two-time major champion Collin Morikawa and Team USA stalwart Rickie Fowler with Sepp Straka.
Lowry says the emotional toll the competition brings is actually inspiring:
Masters champion Jon Rahm will lead the way for the third consecutive Ryder Cup tomorrow after being sent to partner Tyrrell Hatton.
Rory McIlroy and Tommy Fleetwood meanwhile will pair up on the opening day in Rome.
They'll play against American duo of Xander Schauffele and Patrick Cantlay in the foursomes.
While Viktor Hovland partners Ryder Cup debutant, Ludvig Aberg.
They'll face Brian Harman and Max Homa.
Tee Times and Pairings:
Team Europe: Jon Rahm and Tyrrell Hatton
Team USA: Scottie Scheffler and Sam Burns
Team Europe: Viktor Hovland and Ludvig Aberg
Team USA: Brian Harman and Max Homa
Team Europe: Shane Lowry and Sepp Straka
Team USA: Rickie Fowler and Collin Morikawa
Team Europe: Rory McIlroy and Tommy Fleetwood
Team USA: Xander Schauffele and Patrick Cantlay